The bi-annual event, which raises funds for the charity, will see the likes of Gordon Ramsay, James Corden and Ben Shepherd compete against footballing legends Alan Shearer, David Seaman and Henrik Larsson.
"I am so excited Soccer Aid is back. It will be a great time for football, with World Cup fever at boiling point," Williams told the Daily Express.
The event will be broadcast live on ITV1 on 6 June.
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