Hopkins joins Melville GES from Ocean Media where she was senior sales executive on the Boat & Caravan Show.
She has previously worked for Expo Management and the Australian Direct Marketing Association in Sydney.
GES's chief operating officer Andy Gibb said Hopkins joins the company at a time of "unprecedented growth".
"We're delighted to welcome her to the team," he said. "We're confident that Kylie's experience in all four corners of the events industry is going to be a valuable asset to Melville GES, helping us to deliver our trademark integrated events service to our growing list of clients."
As reported by Event, Gibb left Ocean Media in December to join Melville.
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